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Bohr,
Niels; Kramers, Hendrik, Anthony; and Slater, John Clarke. Uber die
Quantentheorie der Strahlung, In Zeitschrift fur Physik, Vol 24, pp.69-
87. Braunschweig and Berlin: Vieweg & Sohn, Springer, 1924. Text in
German. Octavo, early half pebbled cloth over marbled boards. $500.
First
printing of Bohr, Kramers, and Clarke’s influential paper that
“contained drastic theoretical proposals concerning the interaction of
light and matter."
"After
Kramers had succeeded in extending the scope of the correspondence
argument to the theory of optical dispersion - thus rounding off a
treatment of the interaction of atomic systems with radiation that
accounted for all emission, absorption, and scattering processes - Bohr
ventured to propose a systematic formulation of the whole theory, in
which what he called the virtual character of the classical model was
emphasized. In this he was aided by Kramers and a young American
visitor, J. C. Slater, and the new theory was published in 1924 under
the authorship of all three. The most striking feature of this
remarkable paper, 'The Quantum Theory of Radiation,' was the
renunciation of the classical form of causality in favor of a purely
statistical description. Even the distribution of energy and momentum
between the radiation field and the 'virtual oscillators' constituting
the atomic systems was assumed to be statistical, the conservation laws
being fulfilled only on the average. This was going too far: the paper
was hardly in print before A. H. Compton and A. W. Simon had established
by direct experiment the strict conservation of energy and momentum in
an individual process of interaction between atom and radiation.
Nevertheless, this short-lived attempt exerted a profound influence on
the course of events; what remained after its failure was the conviction
that the classical mode of description of the atomic processes had to be
entirely relinquished" (DSB). Band of discoloration to front board
(see photo); stamp to title and endpaper, remnants of library pocket
holder on front pastedown; text fine. |